Is the exact location for North Carolina eighty-one degrees west longitude and thirty-three north latitude?

No, the exact location for North Carolina is not eighty-one degrees west longitude and thirty-three north latitude. North Carolina is located between 75 and 85 degrees west longitude and 34 and 36 degrees north latitude. The state does not extend as far west as 81 degrees west longitude or as far north as 36 degrees north latitude.