No. Venezuela's official language is Spanish. The constitution also recognizes indigenous languages (Wayuu, Warao, Pemón, and ~40 others) for official use in their communities.
French is not an official, regional, or widely spoken language in Venezuela. Small numbers of French expatriates, diplomats, or language students may speak it, but there is no Francophone territory or community comparable to, say, French Guiana (which borders Venezuela but is an overseas department of France).
If you heard "French in Venezuela," it may refer to French Guiana (often confused due to proximity) or to Papiamento (a Portuguese/Spanish-based creole with some French influence) spoken in the ABC islands (Aruba, Bonaire, Curaçao) off Venezuela's coast.