Under the Postal Services Act 2000, intentionally opening or tampering with mail addressed to someone else—including your spouse—without lawful excuse is a criminal offense in the United Kingdom.
Limited exceptions exist, such as reasonable suspicion of fraud or if the addressee is incapacitated. However, these are narrow and fact-specific.
Opening a spouse's mail without permission can also:
If uncertain, consult a solicitor before acting. The legal and relational risks generally outweigh any perceived benefit.