The phrase "Hell hath frozen over" (or "Hell freezes over") is an idiom meaning "something extremely unlikely has happened." It is a hyperbolic expression of surprise, not a reference to a real event. There is no year, date, or historical occurrence associated with it.
Examples of use:
It likely originates from the traditional Christian concept of Hell as a place of eternal fire; its freezing would be a miracle/impossibility. Similar: "pigs fly," "when the moon turns blue."