To find the velocity of the boat with respect to the ground, we add the two vectors:
$$\overrightarrow{v} = \overrightarrow{v_b} + \overrightarrow{v_w}$$
Using the law of cosines, we can find the magnitude of the resultant vector:
$$v = \sqrt{v_b^2 + v_w^2 + 2v_bv_w\cos\theta}$$
where \(\theta\) is the angle between the two vectors. Substituting the given values, we get:
$$v = \sqrt{10^2 + 5^2 + 2(10)(5)\cos90°}$$
$$v = \sqrt{100 + 25 + 0}$$
$$v = \sqrt{125}$$
$$v = 11.18 \text{ km/hr}$$
To find the angle of the resultant vector, we can use the law of sines:
$$\sin\theta = \frac{v_w\sin\theta}{v}$$
Substituting the given values, we get:
$$\sin\theta = \frac{5\sin90°}{11.18}$$
$$\sin\theta = \frac{5}{11.18}$$
$$\theta = \sin^{-1}\left(\frac{5}{11.18}\right)$$
$$\theta = 26.57°$$
Therefore, the velocity of the boat with respect to the stationary ground observer is 11.18 km/hr at an angle of 26.57° north of east.