Empty your black water tank. This allows you to get an accurate reading on the amount of black water and antifreeze you'll eventually have in the tank.
Pour one liter of antifreeze down the toilet. A good rule of thumb is one-to-one; when you have one liter of antifreeze, it should be enough for about one liter of waste. Since your tank started empty, one liter is enough to start off with.
Add another liter of antifreeze after you've deposited about the same amount of black water matter -- flushed materials from your toilet -- into the tank. Keep a tally of how much antifreeze you've added so you know when your mixture is getting too diluted.